Rovers sunk at the Riverside
Doncaster lost their first game of the season whilst hosts Middlesbrough continued with their impressive start.
Goals from Tuncay after 17 minutes and Leroy Lita 71, earned Boro all three points.
Coyne, McMahon, Grounds, Huth, Wheater, Yeates (Aliadiere 72), Johnson, Arca, Williams, Lita (Taylor 85), Emnes (Tuncay 15).
Subs: Steele, Hoyte, Hines, Bennett.
Sullivan, Roberts, Chambers, Stock (c), Lockwood, Hayter, Wilson (Spicer 78), Oster (Fortune 78), Coppinger, Shackell, Shiels (Heffernan 64)
Subs: Smith, Guy, Hird, Dumbuya.
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